PowerToys Workspaces does not natively recognize or manage open Remote Desktop connections as part of its workspace configurations. When you create a workspace, it captures the current state of applications that are open at that moment, but if the Remote Desktop connection is already established, it may not be included in the workspace capture.
To effectively manage your home vs. office configurations using PowerToys Workspaces, you can manually add the Remote Desktop application to your workspace setup. You can do this by launching the Remote Desktop application and then capturing the workspace after it is open. However, keep in mind that if the Remote Desktop connection is already active, it may not reposition as expected when launching the workspace again.
For optimal results, consider using command line interface (CLI) arguments to control the launch behavior of the Remote Desktop application, if applicable.
If you need to frequently switch between configurations, creating separate workspaces for each setup (home and office) might be beneficial, allowing you to quickly launch the desired environment each time.